• 文献标题:   Covalently bonded Fe3O4@SiO2 - reduced graphene oxide nanocomposites as high-efficiency electromagnetic wave absorbers
  • 文献类型:   Article
  • 作  者:   LIU XD, HUANG Y, YAN J, DING L, ZHANG Z, ZHANG N, LIU PB
  • 作者关键词:   covalent bond, reduced graphene oxide, fe3o4@sio2 nanoparticle, impedance matching, em wave absorption performance
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Northwestern Polytech Univ
  • 被引频次:   4
  • DOI:   10.1016/j.ceramint.2019.10.263
  • 出版年:   2020

▎ 摘  要

A novel electromagnetic (EM) wave absorber is synthesized by covalently modifying reduced graphene oxide (rGO) with Fe3O4@SiO2 nanoparticles. The results show that after the amidation reaction, magnetic Fe3O4@SiO(2 )nanoparticles are successfully linked to rGO via amide bonds. The EM wave absorption properties can be adjusted by changing the weight ratio of Fe3O4@SiO2 to rGO. When the ratio is 1:1, the absorber exhibits outstanding absorption performance that the maximum reflection loss (RL) peaks achieve - 55.4 dB at 8.48 GHz, - 55.4 dB at 8.08 GHz and - 52.5 dB at 7.2 GHz with matching thicknesses of 3.5 mm, 3.7 mm and 4.0 mm. The excellent absorption performance can be attributed to good impedance matching and superior attenuation ability. The introduction of amide bonds can act as carrier channels to promote the migration of electrons, change the electron cloud distribution of graphene and adjust EM parameters of absorbers to achieve excellent absorption properties. It provides a new approach to prepare high-efficiency EM wave absorbers.