• 文献标题:   Copper (II) Schiff base-graphene oxide composite as an efficient catalyst for Suzuki-Miyaura reaction
  • 文献类型:   Article
  • 作  者:   ANSARI RM, BHAT BR
  • 作者关键词:   graphene oxide composite, schiff base, chemical grafting, heterogenous catalysi, suzukimiyaura crosscoupling
  • 出版物名称:   CHEMICAL PHYSICS
  • ISSN:   0301-0104 EI 1873-4421
  • 通讯作者地址:   Natl Inst Technol Karnataka
  • 被引频次:   10
  • DOI:   10.1016/j.chemphys.2018.09.018
  • 出版年:   2019

▎ 摘  要

Transition metal copper (II) Schiff base composite (Cu-NH2-GO) was synthesized using functionalized graphene oxide with (3-aminopropyl) methoxysilane (APTMS). X-ray diffraction, FTIR spectroscopy and thermogravimetric analyses ascertained the incorporation of the copper (II) Schiff base on the functionalized graphene oxide. Scanning electron microscopy and TEM evidences further confirmed the surface morphology of the composite. Catalytic activity study indicated that the synthesized Cu-NH2-GO was active for cross-coupling of aryl halide with phenylboronic acid. Above 84% (4-Iodobenzonitrile) biphenyl conversion could be achieved using Cu-NH2-GO catalyst in the C-C coupling reaction.