• 文献标题:   Preparation of Octadecylamine-Graphene/MgCl2-Supported Ziegler-Natta Catalyst and Its Application in Ethylene Polymerization
  • 文献类型:   Article
  • 作  者:   ZHANG H, LIU JS, ZHANG HX, KO EB, PARK JH, MOON YK, SHIN BK, ZHANG XQ, YOON KB
  • 作者关键词:   polyethylene, graphene, nanocomposite, zieglernatta, insitu polymerization
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Kyungpook Natl Univ
  • 被引频次:   0
  • DOI:   10.1166/jnn.2018.14271
  • 出版年:   2018

▎ 摘  要

A facile coagglomeration method for preparing a long alkyl chain modified graphene oxide (MGO)/MgCl2-supported Ti-based Ziegler-Natta catalyst was reported. The effects of MGO on the catalyst morphology and activity for ethylene polymerization were examined. The resultant polyethylene (PE)/MGO nanocomposites exhibited a layered morphology, with the MGO fillers being well dispersed and exhibiting strong interfacial adhesion to the PE matrix. The thermal stability and mechanical properties of the PE were significantly enhanced with the introduction of a small amount of the MGO filler. Thus, this work provides a facile approach to the production of high-performance PE.