• 文献标题:   Facile and controllable synthesis of Prussian blue nanocubes on TiO2-graphene composite nanosheets for nonenzymatic detection of hydrogen peroxide
  • 文献类型:   Article
  • 作  者:   ZHANG YL, XIE JL, XIAO SX, YANG ZM, PANG PF, BAI W, GAO YT
  • 作者关键词:  
  • 出版物名称:   ANALYTICAL METHODS
  • ISSN:   1759-9660 EI 1759-9679
  • 通讯作者地址:   Yunnan Minzu Univ
  • 被引频次:   9
  • DOI:   10.1039/c4ay02418d
  • 出版年:   2014

▎ 摘  要

A novel nonenzymatic sensor for hydrogen peroxide (H2O2) is developed based on a Nafion/Prussian blue/TiO2-graphene nanocomposite (Nafion/PB/TiO2-GR). The PB/TiO2-GR composite was prepared by the electrodeposition of PB nanocubes on the surface of TiO2-GR composite nanosheets and Nafion was used as a stabilizer. The Nafion/PB/TiO2-GR composite modified glassy carbon electrode (Nafion/PB/TiO2-GR/GCE) shows good electrocatalytic activity in the reduction of H2O2 and is used as an amperometric sensor. The sensor exhibits a linear response for H2O2 over concentrations ranging from 40 nM to 2 mM with a high sensitivity of 480.97 mu A mM(-1) cm(-2) and a low detection limit (S/N = 3) of 8.6 nM. Additionally, the sensor exhibits long-term stability, good reproducibility and anti-interference. This study provides a new kind of nanocomposite modified electrode for electrochemical sensors.