▎ 摘　　要

In this paper, we report a simple and facile self-assembly method to successfully fabricate cationic metal porphyrin -MtTMPyP (Mt= Cobalt (II), Manganese (III), or Iron (III); TMPyP = 5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrin) intercalated into the layer of graphene oxide (GO) by the cooperative effects of electrostatic and pi-pi stacking interaction between positively charged metal porphyrin and negatively charged GO sheets. Followed by reduction with hydrazine vapor, a series of novel 2D MtTMPyP/rGO(n) were fabricated. The as-prepared 2D hybrids were fully characterized and tested as non-noble metal catalysts for oxygen reduction reaction (ORR) in an alkaline medium. The MtTMPyP/rGO(n) hybrids, especially CoTMPyP/rGO(5), demonstrated an improved electrocatalytic activity for ORR and a number of exchanged electrons close to 4-electron reaction, increased stability and excellent tolerance to methanol, showing a potential alternative catalyst for ORR in fuel cells and air batteries. (C) 2017, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.