• 文献标题:   A hybrid supercapacitor constructed by graphene wrapped ordered mesoporous Si based electrode
  • 文献类型:   Article
  • 作  者:   XIANG XY, YOU XH, LIU D, LIU XX, YANG S, QIU Y, TANG HL, XIE ZZ, ZHENG H, LI JS, LI X, QU DY
  • 作者关键词:   lithium ion supercapacitor, silicon oxide, ordered mesoporous structure, reduced graphene oxide
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   3
  • DOI:   10.1016/j.colsurfa.2019.05.036
  • 出版年:   2019

▎ 摘  要

With merit of nano size, meso-porous structure and graphene coating, a nonstoichiometric silicon oxides, SiOx, composited material was fabricated into a newly developed lithium ion supercapacitor as negative electrode in this study. After characterization of this SiOx based material through XRD, XPS, SEM, EDS, TEM, TG and nitrogen adsorption/desorption isotherm, it was coupled with porous active carbon, which acted as positive electrode, to construct a lithium ion hybrid supercapacitor. The hybrid device then exhibited a high stable capacity of 880 mA h g(-1) at the 200 mA g(-1) of applied current density. A reversible specific capacity of 328 mA h g(-1) is observed after 6000 charge and discharge cycles under 5 A g(-1). Furthermore, quite a low, about 4.2 mu A, leakage current is also revealed.