• 文献标题:   Synthesis and characterization of carbon coated LiCo1/3Ni1/3Mn1/3O2 and bio-mass derived graphene like porous carbon electrodes for aqueous Li-ion hybrid supercapacitor
  • 文献类型:   Article
  • 作  者:   RAMKUMAR B, YUVARAJ S, SURENDRAN S, PANDI K, RAMASAMY HV, LEE YS, SELVAN RK
  • 作者关键词:   lihybrid supercapacitor, porous carbon, biomas, layered metal oxide, specific capacity
  • 出版物名称:   JOURNAL OF PHYSICS CHEMISTRY OF SOLIDS
  • ISSN:   0022-3697 EI 1879-2553
  • 通讯作者地址:   Bharathiar Univ
  • 被引频次:   5
  • DOI:   10.1016/j.jpcs.2017.09.012
  • 出版年:   2018

▎ 摘  要

For the fabrication of aqueous Li-ion hybrid supercapacitor, carbon coated LiCo1/3Ni1/3Mn1/3O2 (or LiCo1/3Ni1/3Mn1/3O2@C composite) is synthesized by polymeric precursor method with subsequent thermal decomposition procedures for carbon coating. Graphene like porous carbon is obtained by chemical activation from the biomass of Agave Americana. The XRD analysis reveals that LiCo1/3Ni1/3Mn1/3O2 is having a hexagonal layered structure and activated carbon exists in both amorphous and graphitic nature. The TEM image infers that LiCo1/3Ni1/3Mn1/3O2 particles having the non-uniform shape with sub-micron size and the LiCo1/3Ni1/3Mn1/3O2 particles are embedded into amorphous carbon cloud in the composite. The activated carbon shows the specific surface area of 1219 m(2) g(-1). Finally, the fabricated aqueous LiCo1/3Ni1/3Mn1/3O2@C parallel to AC hybrid supercapacitor delivers the specific capacitance of 56 F g(-1) with good capacity retention even after 5000 cycles.