• 文献标题:   Reduced graphene oxide supported ZnO/CdS heterojunction enhances photocatalytic removal efficiency of hexavalent chromium from aqueous solution
  • 文献类型:   Article
  • 作  者:   ZHAO YT, LI L, ZUO YJ, HE GY, CHEN Q, MENG Q, CHEN HQ
  • 作者关键词:   cds/zno heterojunction, graphene, photocatalytic, hexavalent chromium, wastewater
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:  
  • 被引频次:   32
  • DOI:   10.1016/j.chemosphere.2021.131738 EA AUG 2021
  • 出版年:   2022

▎ 摘  要

The removal of toxic and harmful heavy metal contaminants from wastewater is of great importance for global environmental health. The development of efficient photocatalysts is attracting increasing interest with a current focus on material design for improved efficiency. Accordingly, this study aims to optimize the conformation of nanocomposite prepared from a CdS/ZnO heterojunction on reduced graphene oxide (RGO) for boosting the photocatalytic removal of heavy metal contaminants of aqueous systems. Under visible light, the candidate nanocomposites exhibited a range of photocatalytic activity in reducing hexavalent chromium [Cr(VI)] to trivalent chromium [Cr(III)] at room temperature. Among these different nanocomposites, the photocatalytic removal rate constant of Cr(VI) ranged as follows: ZnO/CdS6:5/RGO(6) (0.106 min(-1)) > ZnO/CdS6:5 (0.0630 min(-1)) > CdS (0.0335 min(-1)) > ZnO (0.00121 min(-1)). Moreover, after five cycles of use, the photocatalytic reduction rate of ZnO/CdS6:5/RGO(6) was 93.2 %, which signifies its strong re-cycling performance. These results reveal the feasibility of using CdS/ZnO6:5/RGO(6) to reduce heavy metal ions from wastewater and provide insights for efficiently removing heavy metal ions without additional chemical trapping agents in the photo catalytic process.