▎ 摘 要
The removal of toxic and harmful heavy metal contaminants from wastewater is of great importance for global environmental health. The development of efficient photocatalysts is attracting increasing interest with a current focus on material design for improved efficiency. Accordingly, this study aims to optimize the conformation of nanocomposite prepared from a CdS/ZnO heterojunction on reduced graphene oxide (RGO) for boosting the photocatalytic removal of heavy metal contaminants of aqueous systems. Under visible light, the candidate nanocomposites exhibited a range of photocatalytic activity in reducing hexavalent chromium [Cr(VI)] to trivalent chromium [Cr(III)] at room temperature. Among these different nanocomposites, the photocatalytic removal rate constant of Cr(VI) ranged as follows: ZnO/CdS6:5/RGO(6) (0.106 min(-1)) > ZnO/CdS6:5 (0.0630 min(-1)) > CdS (0.0335 min(-1)) > ZnO (0.00121 min(-1)). Moreover, after five cycles of use, the photocatalytic reduction rate of ZnO/CdS6:5/RGO(6) was 93.2 %, which signifies its strong re-cycling performance. These results reveal the feasibility of using CdS/ZnO6:5/RGO(6) to reduce heavy metal ions from wastewater and provide insights for efficiently removing heavy metal ions without additional chemical trapping agents in the photo catalytic process.