• 文献标题:   Temperature Dependence of Thermal Conductivity of Giant-Scale Supported Monolayer Graphene
  • 文献类型:   Article
  • 作  者:   LIU J, LI P, XU S, XIE YS, WANG Q, MA L
  • 作者关键词:   giantscale graphene, thermal conductivity, supported by pmma, compressive strain
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/nano12162799
  • 出版年:   2022

▎ 摘  要

Past work has focused on the thermal properties of microscale/nanoscale suspended/supported graphene. However, for the thermal design of graphene-based devices, the thermal properties of giant-scale (similar to mm) graphene, which reflects the effect of grains, must also be investigated and are critical. In this work, the thermal conductivity variation with temperature of giant-scale chemical vapor decomposition (CVD) graphene supported by poly(methyl methacrylate) (PMMA) is characterized using the differential transient electrothermal technique (diff-TET). Compared to the commonly used optothermal Raman technique, diff-TET employs joule heating as the heating source, a situation under which the temperature difference between optical phonons and acoustic phonons is eased. The thermal conductivity of single-layer graphene (SLG) supported by PMMA was measured as 743 +/- 167 W/(m.K) and 287 +/- 63 W/(m.K) at 296 K and 125 K, respectively. As temperature decreased from 296 K to 275 K, the thermal conductivity of graphene was decreased by 36.5%, which can be partly explained by compressive strain buildup in graphene due to the thermal expansion mismatch.