• 文献标题:   Hydrophilic graphene quantum dots as turn-off fluorescent nanoprobes for toxic heavy metal ions detection in aqueous media
  • 文献类型:   Article
  • 作  者:   ANUSUYA T, KUMAR V, KUMAR V
  • 作者关键词:   graphene quantum dot, optical nanosensor, fluorescence quenching, toxic heavy metal ion
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:  
  • 被引频次:   27
  • DOI:   10.1016/j.chemosphere.2021.131019 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

Y Efforts are being made to develop fast, cost-effective and sensitive sensor to detect water contamination by toxic heavy metal ions. The oxygenated functional groups decorated graphene quantum dots (GQDs) effectively enhances the aqueous solubility and considered as a more desirable and simple sensing material with high sensitivity. Here, photoluminescence (PL) property of GQDs has been employed to devise an optical nanosensor for the detection of toxic heavy metal ions in aqueous media. Hydrothermal method was employed to synthesize highly fluorescent and water soluble GQDs. The fluorescence intensity reduces with the increase in toxic heavy metal ions concentration. The observed PL was analyzed by the Stern-Volmer equation to study the fluorescent quenching mechanism of the system. Nonlinear behavior of Stern-Volmer plot suggests that the reduction in the fluorescent intensity is due to the combination of dynamic and static processes. The fluorescence quenching results showed that, the as synthesized GQDs are an efficient fluorescent probe for heavy metal ions viz. Hg2+, Cd2+ and Pb2+ with the detection limit of 1.171 mu M, 2.455 mu M and 2.011 mu M respectively. This study shows the viability of GQDs as promising material for sensing the heavy metal ions in aqueous solution.