• 文献标题:   Liquid-phase exfoliation of graphene in organic solvents with addition of naphthalene
  • 文献类型:   Article
  • 作  者:   XU JS, DANG DK, TRAN VT, LIU XY, CHUNG JS, HUR SH, CHOI WM, KIM EJ, KOHL PA
  • 作者关键词:   graphene, naphthalene, pipi interaction, liquidphase exfoliation
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   36
  • DOI:   10.1016/j.jcis.2013.12.009
  • 出版年:   2014

▎ 摘  要

We report a facile method for the production of graphene sheets through liquid-phase exfoliation of graphite in organic solvents with addition of naphthalene. The production yield of graphene is significantly increased with the addition of naphthalene in most solvents tested in this work. Naphthalene serves as a "molecular wedge" to intercalate into the edge of graphite, which plays a key role during sonication and significantly improves the production yield of graphene. The graphene concentration of the dispersion in 1-methyl-2-pyrrolidinone is as high as 0.15 mg/mL (after sonication for 90 min), which allows this method to easily produce films and composites for a range of applications. (C) 2013 Elsevier Inc. All rights reserved.