• 文献标题:   Ultrafast-Selective Nanofiltration of an Hybrid Membrane Comprising Laminated Reduced Graphene Oxide/Graphene Oxide Nanoribbons
  • 文献类型:   Article
  • 作  者:   CHO KM, LEE HJ, NAM YT, KIM YJ, KIM C, KANG KM, TORRES CAR, KIM DW, JUNG HT
  • 作者关键词:   nanofiltration, membrane, graphene, graphene nanoribbon, composite
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Korea Adv Inst Sci Technol
  • 被引频次:   11
  • DOI:   10.1021/acsami.9b09037
  • 出版年:   2019

▎ 摘  要

In this study, reduced graphene oxide (rGO) and graphene oxide nanoribbons (GONRs) are used to fabricate a composite membrane that exhibits ultrafast water permeance (312.8 L m(-2) h(-1) bar(-1)) and precise molecular separation (molecular weight cutoff: 269 Da), which surpass the upper bound of previously reported polymer and graphene-based nanofiltration membranes. As two-dimensional GONR exhibits a width on the scale of nanometers, its nanochannels can be enlarged without hindering the stacking of rGO. Moreover, abundant oxygen-containing groups on the edge and surface of GONR enhance the electrostatic interactions between the filtered molecules and the membrane nanochannel. By the synergistic effect, rejection and water flux are considerably increased. Owing to the chemically stable nature of rGO, the composite membrane is highly stable in aqueous media (from acidic to alkaline) and is recyclable during repeated filtration tests.