• 文献标题:   Reduced Graphene Oxide as a Solid-State Electron Mediator in Z-Scheme Photocatalytic Water Splitting under Visible Light
  • 文献类型:   Article
  • 作  者:   IWASE A, NG YH, ISHIGURO Y, KUDO A, AMAL R
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  • ISSN:   0002-7863
  • 通讯作者地址:   Univ New S Wales
  • 被引频次:   591
  • DOI:   10.1021/ja203296z
  • 出版年:   2011

▎ 摘  要

The effectiveness of reduced graphene oxide as a solid electron mediator for water splitting in the Z-scheme photocatalysis system is demonstrated. We show that a tailor-made, photoreduced graphene oxide can shuttle photogenerated electrons from an O(2)-evolving photocatalyst (BiVO(4)) to a H(2)-evolving photocatalyst (Ru/SrTiO(3): Rh), tripling the consumption of electron hole pairs in the water splitting reaction under visible-light irradiation.