• 文献标题:   A High Sensitive TNT Sensor Based on Electrochemically Reduced Graphene Oxide-Poly(amidoamine) Modified Electrode
  • 文献类型:   Article
  • 作  者:   SHAMSIPUR M, TABRIZI MA, MAHKAM M, ABOUDI J
  • 作者关键词:   2 4 6tirnitrotoluene, ergopamam, electrochemical sensor, jacksonmeisenheimer complex
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Razi Univ
  • 被引频次:   17
  • DOI:   10.1002/elan.201400634
  • 出版年:   2015

▎ 摘  要

In this paper, the electrochemically reduced graphene oxide-poly(amidoamine) hybrid (ErGO-PAMAM) have been used for fabrication of TNT electrochemical sensor. The prepared modified electrode is characterized with X-ray photoelectron spectroscopy (XPS), fourier transform infrared spectroscopy (FT-IR), electrochemical impedance spectroscopy (EIS), energy-dispersive X-ray (EDX) spectroscopy, scanning electron microscopy (SEM) and atomic force microscope (AFM). Based on obtained results, it is can be seen that the ErGO-PAMAM/GCE has high response to TNT than the other graphene based modified electrodes. The resulting electrochemical sensor exhibited good response to TNT with linear range from 0.05 to 1.2 ppm with a low detection limit of 0.0015 ppm.