• 文献标题:   The Regulating Role of Carbon Nanotubes and Graphene in Lithium-Ion and Lithium-Sulfur Batteries
  • 文献类型:   Review
  • 作  者:   FANG RP, CHEN K, YIN LC, SUN ZH, LI F, CHENG HM
  • 作者关键词:   batterie, carbon nanotube, graphene, lithium
  • 出版物名称:   ADVANCED MATERIALS
  • ISSN:   0935-9648 EI 1521-4095
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   99
  • DOI:   10.1002/adma.201800863
  • 出版年:   2019

▎ 摘  要

The ever-increasing demands for batteries with high energy densities to power the portable electronics with increased power consumption and to advance vehicle electrification and grid energy storage have propelled lithium battery technology to a position of tremendous importance. Carbon nanotubes (CNTs) and graphene, known with many appealing properties, are investigated intensely for improving the performance of lithium-ion (Li-ion) and lithium-sulfur (Li-S) batteries. However, a general and objective understanding of their actual role in Li-ion and Li-S batteries is lacking. It is recognized that CNTs and graphene are not appropriate active lithium storage materials, but are more like a regulator: they do not electrochemically react with lithium ions and electrons, but serve to regulate the lithium storage behavior of a specific electroactive material and increase the range of applications of a lithium battery. First, metrics for the evaluation of lithium batteries are discussed, based on which the regulating role of CNTs and graphene in Li-ion and Li-S batteries is comprehensively considered from fundamental electrochemical reactions to electrode structure and integral cell design. Finally, perspectives on how CNTs and graphene can further contribute to the development of lithium batteries are presented.