• 文献标题:   Nanodiamond-Core-Reinforced, Graphene-Shell-Immobilized Platinum Nanoparticles as a Highly Active Catalyst for the Low-Temperature Dehydrogenation of n-Butane
  • 文献类型:   Article
  • 作  者:   ZHANG JY, CAI XB, WU KH, ZHANG YJ, WANG J, DIAO JY, WANG N, LIU HY, SU DS
  • 作者关键词:   dehydrogenation, graphene, hybrid carbon, nanoparticle, platinum
  • 出版物名称:   CHEMCATCHEM
  • ISSN:   1867-3880 EI 1867-3899
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   3
  • DOI:   10.1002/cctc.201701231
  • 出版年:   2018

▎ 摘  要

Pt nanoparticles (NPs) immobilized on a core-shell hybrid carbon support allow the efficient direct dehydrogenation of n-butane at low temperatures. The hybrid carbon support is composed of a nanodiamond core and a reinforced ultrathin graphene shell (ND@G), which improves the stability of the anchored Pt NPs against sintering under the reaction conditions. The as-prepared Pt/ND@G catalyst demonstrates excellent catalytic performance (approximate to 25% conversion with > 95% selectivity toward olefins) at 450 degrees C for over 10h as a result of strong metal-support interactions. The catalyst can also be fully regenerated by postoxidative thermal treatment.