• 文献标题:   Synthesis of modified gum tragacanth/graphene oxide composite hydrogel for heavy metal ions removal and preparation of silver nanocomposite for antibacterial activity
  • 文献类型:   Article
  • 作  者:   SAHRAEI R, GHAEMY M
  • 作者关键词:   gum tragacanth, graphene oxide, composite hydrogel, heavy metal ion, silver nanoparticle, antibacterial activity
  • 出版物名称:   CARBOHYDRATE POLYMERS
  • ISSN:   0144-8617 EI 1879-1344
  • 通讯作者地址:   Univ Mazandaran
  • 被引频次:   54
  • DOI:   10.1016/j.carbpol.2016.10.059
  • 出版年:   2017

▎ 摘  要

New composite hydrogels were synthesized based on gum tragacanth (GT) carbohydrate and graphene oxide (GO). GT was sulfonic acid-functionalized and cross-linked by using 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and N,N'-methylenebisacrylamide (MBA) monomers and ceric ammonium nitrate (CAN) as an initiator. The prepared hydrogels were characterized by Fourier transform infrared spectrum (FT-IR), field emission scanning electron microscope (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Adsorption process for removal of heavy metal ions has followed the pseudo-first-order kinetic model and fitted well with the Langmuir model. The maximum adsorption capacity (Q(m)) was 142.50,112.50 and 132.12 mg g(-1) for Pb(II), Cd(II), and Ag(I), respectively. The removal percentage decreased slightly after several adsorption/desorption cycles. The adsorbed Ag(l) ions in hydrogel were transformed to Ag-0 nanoparticles (with a narrow distribution and mean size of 13.0 nm) by using Achillea millefolium flower extract. The antibacterial performance of the Ag-0 nanocomposite hydrogel was also investigated. (C) 2016 Elsevier Ltd. All rights reserved.