• 文献标题:   Synthesis of Li2MnSiO4-Graphene Composite and Its Electrochemical Performances as a Cathode Material for Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   KIM J, SONG T, PARK H, YUH J, PAIK U
  • 作者关键词:   li2mnsio4, graphene, cathode, li ion batterie
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Hanyang Univ
  • 被引频次:   5
  • DOI:   10.1166/jnn.2014.9390
  • 出版年:   2014

▎ 摘  要

The Li2MnSiO4 is a promising candidate as a cathode for lithium ion batteries due to its large theoretical capacity of 330 mA h g(-1) and high thermal stability. However, the problems related to low electronic conductivity and large irreversible capacity at the first cycle limits its practical use as a Li-ion cathode material. We have developed a carbon coated Li2MnSiO4-graphene composite electrode to overcome these problems. Our designed electrode exhibits high reversible capacity of 301 mA h g(-1), with a high initial coulombic efficiency, and a discharge capacity at current rate of 0.5 C, that is double value of carbon coated Li2MnSiO4-carbon black composite electrode. These significant improvements are attributed to fast electron transport along the graphene sheet.