• 文献标题:   The role of defects and dimensionality in influencing the charge, capacitance, and energy storage of graphene and 2D materials
  • 文献类型:   Review
  • 作  者:   BANDARU PR, YAMADA H, NARAYANAN R, HOEFER M
  • 作者关键词:   2d material, capacitance, defect, energy storage, graphene
  • 出版物名称:   NANOTECHNOLOGY REVIEWS
  • ISSN:   2191-9089 EI 2191-9097
  • 通讯作者地址:   Univ Calif San Diego
  • 被引频次:   0
  • DOI:   10.1515/ntrev-2016-0099
  • 出版年:   2017

▎ 摘  要

The inevitable presence of defects in graphene and other two-dimensional (2D) materials influences the charge density and distribution along with the concomitant measured capacitance and the related energy density. We review, in this paper, the various manifestations of the capacitance including both the classical electrostatic (e.g. associated with double layer, space charge, chemical capacitances) and the quantum forms, as well as a few methodologies to tune the respective capacitances. The role of a proper determination of the surface area of 2D materials, considering the presence of defects, in determining the capacitance and the magnitude of the energy storage is also considered.