• 文献标题:   Electrodeposited reduced-graphene oxide/cobalt oxide electrodes for charge storage applications
  • 文献类型:   Article
  • 作  者:   GARCIAGOMEZ A, EUGENIO S, DUARTE RG, SILVA TM, CARMEZIM MJ, MONTEMOR MF
  • 作者关键词:   electrodeposition, reducedgraphene oxide, cobalt oxide, charge storage electrode
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Univ Lisbon
  • 被引频次:   14
  • DOI:   10.1016/j.apsusc.2016.04.113
  • 出版年:   2016

▎ 摘  要

In the present work, electrochemically reduced-graphene oxide/cobalt oxide composites for charge storage electrodes were prepared by a one-step pulsed electrodeposition route on stainless steel current collectors and after that submitted to a thermal treatment at 200 degrees C. A detailed physico-chemical characterization was performed by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and Raman spectroscopy. The electrochemical response of the composite electrodes was studied by cyclic voltammetry and charge-discharge curves and related to the morphological and phase composition changes induced by the thermal treatment. The results revealed that the composites were promising materials for charge storage electrodes for application in redox supercapacitors, attaining specific capacitances around 430 F g(-1) at 1 A g(-1) and presenting long-term cycling stability. (C) 2016 Elsevier B.V. All rights reserved.