▎ 摘　　要

In this paper, a Li2MnSiO4/carbon/graphene (LMS/C/G) composite is synthesized by a facile one-step synthesis method and shows superior high-rate performances as the cathode materials for lithium ion batteries (LIBs). In the LMS/C/G composite, carbon coated Li2MnSiO4 particles, with sizes of 20-30 nm, are uniformly anchored on graphene nanosheets. When assembled as the cathodes of LIBs and charge-discharged at the high rates of 1 C, 2 C, 5 C and 10 C (1 C = 166mA g(-1)), the specific discharge capacities of the LMS/C/G composite can reach 210, 181, 143, and 109 mAh g(-1), respectively. These electrochemical performances are much better than the performances of the Li2MnSiO4 composites that simply coated with carbon (LMS/C) or merely wrapped by graphene sheets (LMS/G). Electrochemical impedance spectroscopy (EIS) analysis shows that, compared with composites LMS/G and LMS/C, composite LMS/C/G has smaller charge-transfer resistance through the solid-electrolyte interfaces and faster lithium ions diffusion coefficient in the cathode materials. These much improved electronic and ionic conductivities should account for the superior high-rate performances of the LMS/C/G composite. (C) 2014 Elsevier Ltd. All rights reserved.