• 文献标题:   Development of photoluminescent artificial nacre-like nanocomposite from polyester resin and graphene oxide
  • 文献类型:   Article
  • 作  者:   HAMEED A, SNARI RM, ALAYSUY O, ALLUHAYBI AA, ALHASANI M, ABUMELHA HM, ELMETWALY NM
  • 作者关键词:   lanthanidedoped strontium aluminate, photoluminescence, smart artificial nacre, superhydrophobic, unsaturated polyester
  • 出版物名称:   MICROSCOPY RESEARCH TECHNIQUE
  • ISSN:   1059-910X EI 1097-0029
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1002/jemt.24169 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

Long-lasting phosphorescent nacre-like material was simply prepared from a nanocomposite of inorganic and organic materials. Low molecular weight unsaturated polyester (PET), graphene oxide (GO), and nanoparticles of rare-earth activated aluminate pigment were used in the preparation process of an organic/inorganic hybrid nanocomposite. Using methylethylketone peroxide (MEKP) as a hardener, we were able to develop a fluid solution that hardens within minutes at room temperature. Covalent and hydrogen bonds were introduced between the polyester resin and graphene oxide nanosheets. The interface interactions of those bonds resulted in toughness, excellent tensile strength, and high durability. The produced nacre substrates demonstrated long-persistent and reversible luminescence. The excitation of the produced nacre substrates at 365 nm resulted in a 524 nm emission. After being exposed to UV light, the photoluminescent nacre substrates became green. The increased superhydrophobic activity of the produced nacre substrates was achieved without affecting their physico-mechanical properties.