▎ 摘　　要

Lightweight and mechanically compliant energy storage devices have attracted tremendous interest due to the increasing demand for flexible and miniaturized electronics. Recently, microsupercapacitors (MSCs) have advanced rapidly as potential micro-sized power sources, but it is still challenging to build the micro-device using cost-effective technologies for large-scale manufacture. Here, we developed a simple solution-processible method to fabricate microelectrode patterns using a water-dispersible graphene/sulfonated polyaniline (rG/SP) as the active MSC material. The highly stabilized rG/SP dispersion in aqueous solution enables the direct thin-film deposition on flexible substrates and the formation of interdigital patterns by plasma etching. The as-fabricated solid-state MSC delivers an ultrahigh areal capacitance of 3.31 mF/cm(2) and volumetric stack capacitance of 16.55 F/cm(3) with excellent rate and cycling performance. Furthermore, the rG/SP based MSC demonstrates a superior energy density of 1.51 mW h/cm(3) while maintaining high power density. The micro-device also shows superior mechanical stability with 96.5% of capacitance retained under different bending and twisting conditions, which makes it suitable specifically for portable and wearable electronic applications. (C) 2015 Published by Elsevier Ltd.