▎ 摘　　要

Acid catalysts are essential for various chemical reactions in the industrial hydrocarbon chemistry. Sulfonated carbon has shown promising application as a new, cheap and environmentally friendly solid acid catalyst. In this study, we prepared the sulfonated graphene acid catalyst, and it was characterized by electron microscopy, Raman spectroscopy, solid state C-13 MAS NMR, energy dispersive spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). Catalytic hydrolysis of ethyl acetate shows that the sulfonated graphene has highly catalytic activity and can be repetitively used as a water-tolerant solid acid catalyst.