• 文献标题:   The Formation of Nanoscale Closed Graphene Surfaces during Fullerite C-60 Hot Isostatic Pressing
  • 文献类型:   Article
  • 作  者:   SIVKOV DV, PETROVA OV, NEKIPELOV SV, VINOGRADOV AS, SKANDAKOV RN, BAKINA KA, ISAENKO SI, OB EDKOV AM, KAVERIN BS, SIVKOV VN
  • 作者关键词:   xps, nexafs, xrd, raman spectroscopy, fullerite c60, hip treatment
  • 出版物名称:   APPLIED SCIENCESBASEL
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.3390/app112411646
  • 出版年:   2021

▎ 摘  要

The fullerite C-60 modified by hot isostatic pressing (HIP) at 0.1 GPa in argon near and beyond its thermal stability region (920-1270 K temperature interval) was studied by X-ray diffractometry, Raman spectroscopy, ultra soft X-ray photoelectron and near edge X-ray absorption fine structure spectroscopy. It was found that the C-60 molecules merge into closed nanocapsules with a graphene surface during the thermal treatment. The conducted studies showed that using HIP treatment of the fullerite C-60, it is possible to obtain a chemically resistant material with a high hardness and elasticity, as well as a density lower than that of the graphite. This new material, consisting of closed graphene nanocapsules 2-5 nm in size, formed by sp(2) covalent bonds between carbon atoms is promising for various applications, and as a basis for the synthesis of new composite materials.