▎ 摘 要
The fullerite C-60 modified by hot isostatic pressing (HIP) at 0.1 GPa in argon near and beyond its thermal stability region (920-1270 K temperature interval) was studied by X-ray diffractometry, Raman spectroscopy, ultra soft X-ray photoelectron and near edge X-ray absorption fine structure spectroscopy. It was found that the C-60 molecules merge into closed nanocapsules with a graphene surface during the thermal treatment. The conducted studies showed that using HIP treatment of the fullerite C-60, it is possible to obtain a chemically resistant material with a high hardness and elasticity, as well as a density lower than that of the graphite. This new material, consisting of closed graphene nanocapsules 2-5 nm in size, formed by sp(2) covalent bonds between carbon atoms is promising for various applications, and as a basis for the synthesis of new composite materials.