• 文献标题:   Graphene oxide-aluminium oxyhydroxide interaction and its application for the effective adsorption of fluoride
  • 文献类型:   Article
  • 作  者:   BARATHI M, KUMAR ASK, KUMAR CU, RAJESH N
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Birla Inst Technol Sci
  • 被引频次:   64
  • DOI:   10.1039/c4ra10006a
  • 出版年:   2014

▎ 摘  要

A novel aluminium oxy hydroxide [Al-O(OH)] modified graphene oxide was prepared by a chemical precipitation method wherein Al3+ ions could interact effectively with the different functional groups of graphene oxide (GO). The prepared (GO-Al-O(OH) adsorbent was tested for the effective defluoridation of water. The Al3+ modified graphene oxide adsorbent was characterized using FT-IR, FT-Raman, SEMEDS, XRD and XPS studies. The thermodynamically feasible adsorption is supported by the pseudo second order kinetics and a high Langmuir maximum adsorption capacity (51.42 mg g(-1)) for the GO-Al-O(OH) adsorbent. Furthermore, we could treat 2.0 L of 5.0 mg L-1 fluoride ion solution to bring the level within the permissible limits and the regeneration of the adsorbent was done using ammonium hydroxide.