• 文献标题:   Properties of reduced graphene oxide for Mg-air battery
  • 文献类型:   Article
  • 作  者:   MA JL, QIN CH, LI YQ, REN FZ, LIU Y, WANG GX
  • 作者关键词:   mg anode, air battery, graphene, corrosion, mn3o4 nanometer cathode, corrosion inhibitor
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Henan Univ Sci Technol
  • 被引频次:   13
  • DOI:   10.1016/j.jpowsour.2019.05.034
  • 出版年:   2019

▎ 摘  要

In order to decrease the corrosion rate of magnesium anode and increase the discharge property of magnesium-air battery, a water soluble graphene poly (sodium 4-styrenesulfonate)/reduced graphene oxide and a reduced graphene oxide/Mn3O4 nanometer composite are prepared successfully. They are used to assemble a magnesium-air battery with a poly (sodium 4-styrenesulfonate)/reduced graphene oxide based NaCl electrolyte and a reduced graphene oxide/Mn3O4 nanometer composite as cathode catalyst. The structures and morphologies of poly (sodium 4-styrenesulfonate)/reduced graphene oxide and reduced graphene oxide/Mn3O4 nanometer composite are tested by x-ray diffraction, scanning electron microscope and fourier transform infrared spectrophotometer. The assembled magnesium-air battery with poly (sodium 4-styrenesulfonate)/reduced graphene oxide and reduced graphene oxide/Mn3O4 nanometer composite has been found to possess an energy density of 1620 Wh kg(-1) and an anode utilization of 82%, much higher than those achieved with a NaCl solution and a commercial air cathode (1115 Wh kg(-1) and 52%).