• 文献标题:   Real-Time Modulation of Hydrogen Evolution Activity of Graphene Electrodes Using Mechanical Strain
  • 文献类型:   Article
  • 作  者:   KIM MA, SORESCU DC, AMEMIYA S, JORDAN KD, LIU HT
  • 作者关键词:   mechanical strain, electrochemistry, hydrogen evolution reaction her, graphene, density functional theory
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1021/acsami.1c21821 EA FEB 2022
  • 出版年:   2022

▎ 摘  要

This paper reports the effect of mechanically applied elastic strain on the hydrogen evolution reaction (HER) activity of graphene under acidic conditions. An applied tensile strain of 0.2% on a graphene electrode is shown to lead to a 1-3% increase in the HER current. The tensile strain increases HER activity, whereas compressive strain decreases it. Density functional theory (DFT) calculations using a periodic graphene slab model predict an increase in the adsorption energy of the H atom with growing tensile strain, consistent with an enhancement of the current density in HER, similar to that observed experimentally.