• 文献标题:   Effect of the electrolyte composition on the corrosion resistance of single-layer CVD-graphene
  • 文献类型:   Article
  • 作  者:   TRIANA A, OLAYA JJ, PRIETO C
  • 作者关键词:   graphene, cvd, oxidation, corrosion resistance
  • 出版物名称:   SURFACES INTERFACES
  • ISSN:   2468-0230
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.surfin.2022.102025 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

The corrosion resistance of a single-layer graphene film synthetized via chemical vapor deposition (CVD) on a polycrystalline copper substrate is studied. The anticorrosive properties were identified by means of electrochemical tests of potentiodynamic polarization and electrochemical impedance spectroscopy in the following environments: (a) 0.5 M H2SO4, (b) 0.5 M HCl, (c) 3.5wt% NaCl + 0.5 M H2SO4, and (d) Na2S2O3 (10(-)4 mol / l) + 5% NaCl + (CH3COOH) 0.50%). For the characterization of the graphene and corrosion products, the following techniques were used: Raman spectroscopy, AUGER electron spectroscopy, X-ray energy dispersion probe (EDS), scanning electron microscopy (SEM), and confocal laser scanning microscopy (CLSM). The corrosion mechanism and the degree of degradation of the graphene are discussed as a function of the corrosive electrolyte.