• 文献标题:   The pre-treatment of copper for graphene synthesis
  • 文献类型:   Article
  • 作  者:   WANG L, FENG W, YANG LQ, ZHANG JH
  • 作者关键词:   graphene, copper, pretreatment, chemicalvapordeposition
  • 出版物名称:   ACTA PHYSICA SINICA
  • ISSN:   1000-3290
  • 通讯作者地址:   Shanghai Univ
  • 被引频次:   5
  • DOI:   10.7498/aps.63.176801
  • 出版年:   2014

▎ 摘  要

Graphene synthesis by chemical-vapor-deposition (CVD) has attracted great interest. As the substrates for graphene growth, copper has become a common choice because its capacity could produce high-quality and uniform monolayer graphene. Morphology and surface conditions of the copper foil have great influence on the quality of the graphene grown on it. Here we report a rapid and effective copper pre-treatment method to improve the quality of graphene. After a pre-etching in 1 mol/L Fe(NO3)(3) aqueous solutions for 90 s, the quality of the copper foil surface has been improved. Compared with the HCl treatment and electro-chemical polishing, Fe(NO3)(3) pre-etching can generate a better result and has been verified to have general applicability for different types of copper foils.