• 文献标题:   Enhanced Adsorption and Photocatalytic Removal of Cationic Dyes in Aqueous Solutions by Ternary Graphene Oxide-TiO2-SiO2 Nanocomposites
  • 文献类型:   Article
  • 作  者:   RANJITH R, MARUTHAMUTHU D, PRABHAVATHI SP, RAJAM PS
  • 作者关键词:   graphene oxide, cationic dye, adsorption, photocatalytic degradation, thermodynamic study
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Bishop Heber Coll
  • 被引频次:   1
  • DOI:   10.1166/jnn.2019.16522
  • 出版年:   2019

▎ 摘  要

In this study, adsorption is an attractive for the removal of industrial dyes from aqueous simulated wastewaters is reported. The ternary graphene oxide-TiO2-SiO2 (GTS) nanocomposite was synthesized by sol-gel method. The as-synthesized nanocomposite was characterized by XRD, BET, FT-IR, SEM-EDAX and TEM analysis. It was found that the synthesised nanocomposite has excellent adsorption and photocatalytic degradation abilities for the removal of cationic dyes, methylene blue (MB) and crystal violet (CV) owing to its homogeneous mesoporosity with a BET surface area of 583.15 m(2)/g. Furthermore, the adsorption mechanism of these cationic dyes follows pseudosecond-order kinetic model. In addition, the GTS nanocomposite showed maximum adsorption efficiency over MB and CV around 384.62 mg/g and 188.68 mg/g respectively. The thermodynamic parameters (Delta G degrees, Delta H degrees, and Delta S degrees) calculated from the temperature dependent isotherms suggested that the adsorption was spontaneous and endothermic in nature. The study on the reusability of the GTS nanocomposite showed that, even after five succeeding cycles, the capacity of the adsorbent was almost identical.