• 文献标题:   Deep eutectic solvent containing 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol immobilized on magnetic graphene oxide as a selective sorbent for dispersive micro-solid phase extraction of cadmium ions
  • 文献类型:   Article, Early Access
  • 作  者:   KARIMI M, DADFARNIA S, SHABANI AMH, VAFAZADEH R
  • 作者关键词:   cadmium, 2 3hydroxy1methylbut2enylideneamino pyridine3ol, dispersive microsolid phase extraction, deep eutectic solvent, magnetic graphene oxide
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:   Yazd Univ
  • 被引频次:   0
  • DOI:   10.1007/s13738-020-02113-8 EA NOV 2020
  • 出版年:  

▎ 摘  要

A sorbent with high selectivity and capacity for cadmium ions was prepared through immobilization of deep eutectic solvent (DES) of ChCl- glycerol containing the ligand 2-(3-hydroxy-1-methylbut-2-enylideneamino)pyridine-3-ol (acacapyrH(2)) on the magnetic graphene oxide. A dispersive micro-solid phase extraction was designed, and the separated/preconcentrated cadmium ion was determined by flow injection flame atomic absorption spectrometry. After the optimization of effective parameters, the method showed linearity in the concentration range of 0.25-15 mu g L-1 with the coefficient of determination (r(2)) of 0.9991 and enhancement factor of 195 for cadmium. The method was very sensitive with the detection limit (defined as 3S(b)/m) of 0.06 mu g L-1. The method was successfully applied to the determination of Cd(II) in water (drinking and river), fruit (lemon, apricot, and peach) and meat (fish, chicken, and cow meat) samples.