• 文献标题:   An Efficient Electrocatalyst by Electroless Cobalt-Nickel-Phosphorus Alloy Plating on Three-Dimensional Graphene for Hydrogen Evolution Reaction
  • 文献类型:   Article
  • 作  者:   LU MY, WANG LY, JIANG B, ZHENG JB
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:   Northwest Univ
  • 被引频次:   3
  • DOI:   10.1149/2.1261902jes
  • 出版年:   2019

▎ 摘  要

The development of earth-abundant, efficient, and stable electrocatalysts is very important for the hydrogen evolution reaction (HER) in an alkaline electrolyte. An efficient electrocatalyst was fabricated via the electroless plating of well-dispersed Co-Ni-P alloy particles on three-dimensional graphene using nickel foam as the template (Co-Ni-P/rGO/NF). Co-Ni-P/rGO/NF exhibited excellent HER activity with a low overpotential of 65 mV and a small Tafel slope of 63 mV dec(-1) at a current density of 10 mA cm(-2). This catalyst also showed prominent electrochemical durability (over more than 10 h) in an alkaline electrolyte. Therefore, this study provides a facile design for non-noble-metal electrocatalysts, which can be used in future applications to replace Pt-based electrocatalysts. (C) 2019 The Electrochemical Society.