• 文献标题:   Electrochemical detection of hydroquinone by graphene and Pt-graphene hybrid material synthesized through a microwave-assisted chemical reduction process
  • 文献类型:   Article
  • 作  者:   LI J, LIU CY, CHENG C
  • 作者关键词:   hydroquinone, graphene, ptgraphene hybrid material, electrochemical detection, differential pulse voltammetry
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   57
  • DOI:   10.1016/j.electacta.2010.12.046
  • 出版年:   2011

▎ 摘  要

We have synthesized graphene and Pt-graphene hybrid material by a microwave-assisted chemical reduction process and evaluated their application as electrode materials towards the electrochemical detection of hydroquinone. Graphene modified glass carbon electrode (GCE) showed a good performance for detecting hydroquinone due to the unique properties of graphene which increased the active surface area of the electrode and accelerated the electron transfer. The linear detection range of hydroquinone concentration was 20-115 mu M with a sensitivity of 1.38 mu A mu M-1 cm(-2); the detection limit was estimated to be 12 mu M (S/N = 3). The electrocatalytic activity of the Pt-graphene modified GCE was further improved due to the enhanced electron transfer and the linear detection range was 20-145 mu M with the sensitivity of 3.56 mu A mu M-1 cm(-2), detection limit 6 mu M (S/N = 3). (C) 2010 Elsevier Ltd. All rights reserved.