• 文献标题:   Flexible Ti-Doped FeOOH Quantum Dots/Graphene/Bacterial Cellulose Anode for High-Energy Asymmetric Supercapacitors
  • 文献类型:   Article
  • 作  者:   LIU R, MA LN, NIU GD, LI XL, LI EY, BAI Y, LIU Y, YUAN GH
  • 作者关键词:   bacterial cellulose, feooh quantum dot, flexible supercapacitor, tidoping
  • 出版物名称:   PARTICLE PARTICLE SYSTEMS CHARACTERIZATION
  • ISSN:   0934-0866 EI 1521-4117
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   4
  • DOI:   10.1002/ppsc.201700213
  • 出版年:   2017

▎ 摘  要

Ti-doped FeOOH quantum dots (QD) decorated on graphene (GN) sheets are designed and fabricated by a facile and scalable synthesis route. Importantly, the Ti-doped FeOOH QD/GN are successfully dispersed within bacterial cellulose (BC) substrate as bending anode with large loading mass for flexible supercapacitor. By virtue of its favorable architecture, this composite electrode exhibits a remarkable areal capacitance of 3322 mF cm(-2) at 2 mA cm(-2), outstanding cycle performance (94.7% capacitance retention after 6000 cycles), and excellent mechanical strength (68.7 MPa). To push the energy density of flexible supercapacitors, the optimized asymmetric supercapacitor using Mn3O4/GN/BC as positive electrode and Ti-doped FeOOH QD/GN/BC as negative electrode can be cycled reversibly in the operating voltage range of 0-1.8 V and displays ultrahigh areal energy density of 0.541 mWh cm(-2), ultrahigh volumetric energy density of 9.02 mWh cm(-3), reasonable cycling performance (9.4% decay in specific capacitance after 5000 cycles), and good capacitive retention at bending state.