• 文献标题:   Light driven epoxidation of olefins using a graphene oxide/g-C3N4 supported Mo (salen) complex
  • 文献类型:   Article
  • 作  者:   BIAN G, JIANG PP, WANG F, SHEN YR, JIANG KL, LIU L, ZHANG WJ
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Jiangnan Univ
  • 被引频次:   7
  • DOI:   10.1039/c7nj02894f
  • 出版年:   2018

▎ 摘  要

A novel Schiff (Mo) base complex supported on GO surface was successfully prepared, which was further combined with graphitic carbon nitride (g-C3N4) polymer (Mo-GO/g-C3N4) to make it photo-active. The photocatalytic activity of the resulting nano-composite was tested under simulated sunlight (AM 1.5) for the epoxidation of various olefin substrates. In addition, surface photovoltage (SPV) measurements were applied to explore the electron acceleration effect caused by GO and molybdenum. It was demonstrated that both GO and the metal active centers can efficiently accelerate electron transfer, which would finally contribute to the superior catalytic performance.