• 文献标题:   Exfoliated graphene ligands stabilizing copper cations
  • 文献类型:   Article
  • 作  者:   YAMADA Y, MIYAUCHI M, KIM J, HIROSETAKAI K, SATO Y, SUENAGA K, OHBA T, SODESAWA T, SATO S
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223
  • 通讯作者地址:   Chiba Univ
  • 被引频次:   9
  • DOI:   10.1016/j.carbon.2011.03.056
  • 出版年:   2011

▎ 摘  要

Exfoliated graphene ligands were prepared by heating exfoliated graphene sheets in ammonia gas at 1023 K. The functional groups of the functionalized exfoliated graphene ligands were mainly pyridine on the edges of the vacancy defects. Copper cations were coordinated with the ligands. Even after being heated at 773 K, coordinated copper did not show severe agglomeration. On the other hand, copper supported on exfoliated graphene sheets prepared by the conventional method agglomerated and ca. 20 nm of copper oxide was formed. This difference clearly shows that exfoliated graphene ligands stabilized copper cations. (C) 2011 Elsevier Ltd. All rights reserved.