• 文献标题:   Preparation of organically dispersible graphene nanosheet powders through a lyophilization method and their poly(lactic acid) composites
  • 文献类型:   Article
  • 作  者:   CAO YW, FENG JC, WU PY
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   205
  • DOI:   10.1016/j.carbon.2010.06.048
  • 出版年:   2010

▎ 摘  要

Solvent-free graphene nanosheets (GNSs), which are in the form of chemically reduced graphite oxide nanosheets, were prepared using an environmentally friendly freeze drying process. Compared with those produced through the vacuum filtration method, the lyophilized GNS powders were extremely light, loosely packed and could be readily redispersed in appropriate organic media like N,N-dimethylformamide as individual sheets with the aid of sonication. The ability of the as-lyophilized GNS powders to be redispersed in organic solvents facilitates their incorporation into polymers like poly(lactic acid) through a solution-based processing method. In the resulting composite, GNSs were uniformly dispersed in the matrix and enhanced the mechanical and thermal properties of the host polymer, suggesting the great potential of the lyophilized GNS powders in the field of polymer composites. (C) 2010 Elsevier Ltd. All rights reserved.