• 文献标题:   Yielding and flow of highly concentrated, few-layer graphene suspensions
  • 文献类型:   Article
  • 作  者:   BARWICH S, COLEMAN JN, MOBIUS ME
  • 作者关键词:  
  • 出版物名称:   SOFT MATTER
  • ISSN:   1744-683X EI 1744-6848
  • 通讯作者地址:   Univ Dublin Trinity Coll
  • 被引频次:   6
  • DOI:   10.1039/c4sm02855d
  • 出版年:   2015

▎ 摘  要

For a wide range of applications of graphene suspensions, a thorough understanding of their rheological properties is crucial. We probe the microstructure of dense suspensions of micron-sized, few-layer, defect-free graphene platelets by measuring their viscoelastic properties at various concentrations up to 39 mg ml(-1). We propose a model to relate the yield strain to the mesh size of the microstructure as a function of volume fraction phi. From the yield stress measurements we infer the typical bond energy (approximate to 20 k(B)T) and phi dependence of the bond number density. These results allow us to express the steady shear viscosity for Peclet number Pe < 10 in terms of the platelet dimensions, bond energy and phi using a relaxation ansatz.