• 文献标题:   Graphene oxide functionalized with cobalt ferrites applied to the removal of bisphenol A: ionic study, reuse capacity and desorption kinetics
  • 文献类型:   Article, Early Access
  • 作  者:   FACHINA YJ, DE ANDRADE MB, GUERRA ACS, DOS SANTOS TRT, BERGAMASCO R, VIEIRA AMS
  • 作者关键词:   graphene oxide, superparamagnetic nanoparticle, bisphenol a, adsorption, merging contaminant
  • 出版物名称:   ENVIRONMENTAL TECHNOLOGY
  • ISSN:   0959-3330 EI 1479-487X
  • 通讯作者地址:   Univ Estadual Maringa
  • 被引频次:   0
  • DOI:   10.1080/09593330.2020.1830183 EA OCT 2020
  • 出版年:  

▎ 摘  要

A new adsorbent material based on graphene oxide (GO) functionalized with magnetic cobalt ferrite nanoparticles (gamma CoFe2O4) was synthesized via ultrasonication to remove the endocrine-disrupting-chemical bisphenol A (BPA) from aqueous solutions. The synthesized material (GO-gamma CoFe2O4) was characterized by TEM, SEM, DRX and FTIR analysis. Magnetization measures proved that the adsorbent had superparamagnetic characteristics that facilitated its separation from the aqueous solution. The maximum adsorption capacity obtained was 30 mg g(-1)with adsorbent concentration of 1 g L-1, temperature of 55 degrees C and natural pH of the solution. The experimental data were better adjusted to the kinetic models of pseudo-second-order and Langmuir isotherm. The thermodynamic parameters showed that the BPA adsorption on GO-gamma CoFe(2)O(4)was spontaneous, exothermic and thermodynamically favourable. Desorption kinetics was performed using 50% ethanol as solvent, resulting in an equilibrium time of 4 h with better adjustment to the pseudo-second order kinetic model. The adsorbent showed a high regeneration capacity maintaining adsorptive capacity above 75% after 6 cycles of reuse.