▎ 摘　　要

Biocompatible materials with high dielectric constant and low dielectric loss have applications in bio-related electronic devices. Development of flexible materials with those properties is still a challenge. In this work, electrospun membranes and films are prepared from poly(vinyl alcohol) (PVA) and chitosan (CS) solutions, incorporated with a reduced graphene oxide-zinc oxide composite (rGO-ZnO). Blending CS with flexible PVA favors electrospinnability and mechanical properties. ZnO contributes to hinder agglomeration of conductive rGO sheets. The structural, mechanical, dielectric and electrical properties of the hybrid materials are investigated. Infrared spectroscopy reveals interaction between the filler and the polymeric components. For mats and films, the increase in rGO-ZnO content leads to lower crystallinity. The Young's modulus and stress at break values increase with increasing rGO-ZnO content. High dielectric constants (epsilon' = 132 to epsilon' = 166, at 10(3) Hz), associated with low dielectric loss factor (tan delta = 0.02), are determined for the PVA/CS/rGO-ZnO films.