• 文献标题:   One-step reduction and functionalization protocol to synthesize polydopamine wrapping Ag/graphene hybrid for efficient oxidation of hydroquinone to benzoquinone
  • 文献类型:   Article
  • 作  者:   YE WC, SHI XZ, SU J, CHEN Y, FU JJ, ZHAO XJ, ZHOU F, WANG CM, XUE DS
  • 作者关键词:   polydopamine, reduced graphene oxide, silver nanoparticle, simultaneous reduction, oxidation of hydroquinone
  • 出版物名称:   APPLIED CATALYSIS BENVIRONMENTAL
  • ISSN:   0926-3373 EI 1873-3883
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   35
  • DOI:   10.1016/j.apcatb.2014.05.042
  • 出版年:   2014

▎ 摘  要

Based on the excellent properties of dopamine (reduction, self-polymerization and adhesion), we designed a one-step and environment-friendly reduction route to synthesize and simultaneously functionalize polydopamine (PDA)-Ag-reduced graphene oxide (RGO) hybrid. The obtained PDA-Ag-RGO hybrid was characterized by transmission electron microscopy, Raman spectroscopy, X-ray photoelectron spectroscopy, FT-IR and UV-vis analysis. Silver nanoparticles were uniformly dispersed on the surface of RGO sheets and coated with a thin PDA film. The hybrid exhibited good dispersivity in polar solvents (water and acetonitrile). Compared with Ag-RGO hybrid prepared via NaBH4 reduction and commercial Pd/C catalyst, PDA-Ag-RGO hybrid had better catalytic activity for the oxidation of hydroquinone to benzoquinone in the presence of H2O2. Moreover, the hybrid still retained superior catalytic activity over multiple cycles. (C) 2014 Elsevier B.V. All rights reserved.