• 文献标题:   Graphene modified polyacrylonitrile fiber as high-performance cathode for marine sediment microbial fuel cells
  • 文献类型:   Article
  • 作  者:   WANG GC, YU MS, XIE KW, ZHAO RR, FU YB, CHEN TL
  • 作者关键词:   marine sediment microbial fuel cell, graphene, cathode, carbon fiber
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Ocean Univ China
  • 被引频次:   2
  • DOI:   10.1016/j.jpowsour.2019.227002
  • 出版年:   2019

▎ 摘  要

The goal of this study is to make a high-performance cathode in a simple way, so that it can better serve marine sediment microbial fuel cells. We design a cathode by combining graphene with carbon fiber through a binder, and apply it for the first time to these cells, to improve the electrochemical performance of these cells while increasing the specific surface area of the cathode. This cathode shows excellent performance in a laboratory simulated marine environment. The specific surface area of graphene modified polyacrylonitrile fiber cathode reaches 41.13 m(2)/g, 1.5 times larger than that of the blank cathode (26.98 m(2)/g). Its capacitance and exchange current density are 6.1 times and 16.4 times higher than that of theblank cathode, respectively. The anti-polarization ability of the modified cathode was significantly improved, and the maximum power density of the cell equipped with the G/P cathode (2.12 kW/kg) is 6.24 times that of the blank (0.34 kW/kg). In terms of stability, it is quite resistant to prolonged seawater immersion or scouring. This excellent mechanical stability can extend the cells' life and reduce replacement costs.