• 文献标题:   A Mild Strategy to Strengthen Three Dimensional Graphene Aerogel for Supporting Sulfur as a Free-standing Cathode in Lithium-Sulfur Batteries
  • 文献类型:   Article
  • 作  者:   YAN YL, QIN HC, WEI YQ, YANG R, XU YH, CHEN LP, LI QL, SHI MM
  • 作者关键词:   lis batterie, 3d graphene aerogel, ammonia strengthening, electrochemical performance
  • 出版物名称:   BULLETIN OF THE KOREAN CHEMICAL SOCIETY
  • ISSN:   1229-5949
  • 通讯作者地址:   Xian Univ Technol
  • 被引频次:   0
  • DOI:   10.1002/bkcs.11438
  • 出版年:   2018

▎ 摘  要

Recently, three dimensional graphene aerogel (3DGA) supported sulfur microparticles was used as a cathode material for lithium-sulfur batteries, which was considered as one of the most promising next generation rechargeable batteries due to its ultra-high theoretical specific capacity (1675 mAh/g). However, the mechanical strength of 3DGA remains an issue for further application. Herein, a strengthened 3DGA (S3DGA) was achieved by soaking in a low concentration ammonia solution at a relative low temperature. Then the S3DGA loaded sulfur (S3DGA-S) was cut into a round piece and directly used as a cathode without additional binders or conductive additives in Li-S batteries. The mechanical strength, microstructure, and electrochemical properties were investigated by compare with a 3DGA prepared without strengthen. The S3DGA-S presented good mechanical strength, excellent capacity retention, and lower electrochemical impedance.