• 文献标题:   Continuous removal of pharmaceutical drug chloroquine and Safranin-O dye from water using agar-graphene oxide hydrogel: Selective adsorption in batch and fixed-bed experiments
  • 文献类型:   Article
  • 作  者:   DE ARAUJO CMB, WERNKE G, GHISLANDI MG, DIORIO A, VIEIRA MF, BERGAMASCO R, SOBRINHO MAD, RODRIGUES AE
  • 作者关键词:   graphene oxide biocomposite, chloroquine diphosphate, safranino, selective adsorption, adsorption column, water treatment
  • 出版物名称:   ENVIRONMENTAL RESEARCH
  • ISSN:   0013-9351 EI 1096-0953
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.envres.2022.114425 EA OCT 2022
  • 出版年:   2023

▎ 摘  要

In this work, Chloroquine diphosphate, and the cationic dye Safranin-O were selectively removed from water using the agar-graphene oxide (A-GO) hydrogel, produced via simple one-step jellification process. The morphology of the A-GO biocomposite was characterized and batch experiments were performed, with adsorption isotherms satisfactorily fitting (R-2 > 0.98) Sips (Safranin-O) and Freundlich (Chloroquine) isotherms. Driving force models and Fick's diffusion equation were applied to the modeling of kinetic data, and a satisfactory fit was obtained. Selective adsorption carried out in batch indicated that competitive adsorption occurs when both components are mixed in water solution - the adsorptive capacities dropped similar to 10 mg g(-1) for each component, remaining 41 mg g(-1) for safranin-O and 31 mg g(-1) for chloroquine. Fixed-bed breakthrough curves obtained in an adsorption column showed adsorption capacities over 63 mg g(-1) and 100 mg g(-1) for chloroquine and safranin-O, respectively, also exhibiting outstanding regenerative potentials. Overall, the biocomposite produced using graphene oxide proved to be a viable and eco-friendly alternative to continuously remove both contaminants from water.