• 文献标题:   Silicon@graphene composite prepared by spray-drying method as anode for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   SU MR, LIU S, TAO L, TANG YP, DOU AC, LV J, LIU YJ
  • 作者关键词:   lithium ion batterie, silicon@graphene, spherical, spraydrying
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   7
  • DOI:   10.1016/j.jelechem.2019.04.072
  • 出版年:   2019

▎ 摘  要

The silicon@graphene composite as anode material was prepared by a spray-drying method combined with a low temperature reduction technology. XRD results show that the composite is composed of silicon and graphene confirmed by the FT-IR and Raman spectra. SEM and TEM results reveal that the silicon@graphene powders are the spherical shape with micron in diameter and graphene sheets are enwrapped with nano-silicon particles. The silicon@graphene composite shows an improved electrochemical performance, in which the sample can show the best electrochemical performance while the mass ratio of silicon and graphene oxide reaches to 1:4, delivering a high initial charge capacity of 1298.1 mAh g(-1) at 100 mA g(-1). Moreover, the sample can also show good rate performance, which indicates that it could be used as a promising anode material for Li-ion batteries.