• 文献标题:   Improving the electrochemical performance by sulfonation of polyaniline-graphene-silica composite for high performance supercapacitor
  • 文献类型:   Article
  • 作  者:   RAVI B, RAJENDER B, PALANIAPPAN S
  • 作者关键词:   graphene, polyaniline, sulfonation, supercapacitor, ternary composite
  • 出版物名称:   INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS POLYMERIC BIOMATERIALS
  • ISSN:   0091-4037 EI 1563-535X
  • 通讯作者地址:   CSIR Indian Inst Chem Technol
  • 被引频次:   10
  • DOI:   10.1080/00914037.2016.1171221
  • 出版年:   2016

▎ 摘  要

In this work, to increase the specific capacitance and energy density of reduced graphene oxide-silica composite (RGO-SiO2), pseudocapacitive behaviour of polyaniline is introduced to RGO-SiO2(PANI-RGO-SiO2) and further improved by sulfonating the polyaniline system (SPANI-RGO-SiO2). Formation of SPANI-RGO-SiO2 is confirmed from IR and XRD analyses. SPANI-RGO-SiO2 shows nanorods morphology with less crystalline nature. The specific capacitance of RGO-SiO2 is increases from 24 to 780 F g(-1) with sulfonation of polyaniline in RGO-SiO2. Retention in the specific capacitance value of SPANI-RGO-SiO2 is 85% with that of its original value of 780 F g(-1) with coulombic efficiency (96-99%). [GRAPHICS]