• 文献标题:   Fabrication of reduced graphene oxide/TiO2 nanorod/reduced graphene oxide hybrid nanostructures as electrode materials for supercapacitor applications
  • 文献类型:   Article
  • 作  者:   RAMADOSS A, KIM GS, KIM SJ
  • 作者关键词:  
  • 出版物名称:   CRYSTENGCOMM
  • ISSN:   1466-8033
  • 通讯作者地址:   Jeju Natl Univ
  • 被引频次:   59
  • DOI:   10.1039/c3ce41517a
  • 出版年:   2013

▎ 摘  要

Two-dimensional (2D) reduced graphene oxide/titanium dioxide nanorod array/reduced graphene oxide (rGO/TiO2 NR/rGO) with a porous hybrid structure was fabricated as an electrode material for use in electrochemical supercapacitors. The structural, morphological, and compositional characteristics of the resulting electrode material were evaluated by using X-ray diffraction (XRD), Raman spectroscopy, field emission scanning electron microscopy (FE-SEM), and X-ray photoelectron spectroscopy (XPS). The electrochemical behavior of the as-prepared electrodes was characterized by using cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) in 1 M Na2SO4 aqueous electrolyte. The maximum specific capacitance of this rGO/TiO2 NR/rGO electrode was 114.5 F g(-1) at a scan rate of 5 mV s(-1). The electrode exhibited high cycling stability, retaining over 85% of its initial capacitance after 4000 cycles. These results indicate that rGO/TiO2/rGO is a promising candidate for the electrode material in supercapacitor applications.