• 文献标题:   Covalently cyclopalladium(II) complex/reduced-graphene oxide as the effective catalyst for the Suzuki-Miyaura reaction at room temperature
  • 文献类型:   Article
  • 作  者:   FATH RH, HOSEINI SJ
  • 作者关键词:   graphene oxide, palladium nanoparticle, organopalladium complex, catalyst, suzukimiyaura reaction
  • 出版物名称:   JOURNAL OF ORGANOMETALLIC CHEMISTRY
  • ISSN:   0022-328X EI 1872-8561
  • 通讯作者地址:   Univ Yasuj
  • 被引频次:   15
  • DOI:   10.1016/j.jorganchem.2016.11.016
  • 出版年:   2017

▎ 摘  要

In this study, cyclometallated palladium complexes, [Pd(C-N)Cl(L)), in which CN = N(1), C(2')-chelated deprotonated 2-phenylpyridine, ppy, and L = dmso (dimethylsulfoxide) (complex 1) or PPh3 (complex 2), have been synthesized. Also, complex 1 attached to amine functionalized graphene oxide (1-f-GO) has been synthesized by covalently bonding of complex 1 onto the graphene oxide surface through coordination interaction with 3-(aminomethyl)pyridine ligand spacers. The supported catalyst showed enhanced catalytic performance towards Suzuki Miyaura reaction of aryl halides and phenylboronic acid at room temperature compared with the homogeneous analogues, and they could be readily recycled and reused several times without discernible loss of their activity. (C) 2016 Elsevier B.V. All rights reserved.