• 文献标题:   Sandwich-like Sn/SnO2@Graphene anode composite assembled by fortissimo penetration of gamma-ray and interlamellar limitation of graphene oxide
  • 文献类型:   Article
  • 作  者:   JIANG WW, WANG W, LIU LS, WANG HB, XU ZW, LI FY, FU HJ, LV HM, CHEN L, KANG YF
  • 作者关键词:   gammaray irradiation, ultrastrong penetration, interlamellar limitation, sandwichlike structure, sn/sno2 composite, anode
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Tianjin Polytech Univ
  • 被引频次:   10
  • DOI:   10.1016/j.jallcom.2018.11.296
  • 出版年:   2019

▎ 摘  要

In developing high-performance electrode materials for ion batteries, manifold methods to assemble definite structures of graphene-SnOx composite anodes are presented. Here we have firstly put forward an efficient strategy based on fortissimo penetration from gamma-ray irradiation to assemble graphene and Sn/SnO2 composite, which is formed by a large-scale and simple synthesis method. And uniform SnO2 and Sn nanoparticles sandwiched between graphene sheets (sandwich-like Sn/SnO2 @ graphene composite) are fabricated due to the synergism of interlamellar limitation of graphene oxide and ultra-strong penetration and high energy of gamma-ray, which help to improve conductivity of Sn/SnO2 and can prevent Sn/SnO2 agglomeration and volume expansion due to graphene sheets buffed. High initial capacity about 2970.3 mAh g(-1) and stable cycle performance are exhibited. This facile method has potential prospects to offer an attractive alternative approach for preparation of metal nanoparticles/graphene composite as high performance electrodes for Li/Na-ion batteries. (C) 2018 Elsevier B.V. All rights reserved.